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Bio-Diesel

Authored By: D. Cassidy

Biodiesel is a vegetable-based fuel that is appealing, in part, because it confers some potential environmental benefits. Production costs for soy-based diesel currently are extremely high and it faces stiff competition in most petroleum-based diesel fuel markets. For example, in Europe, biobased diesel is more popular because incentives are offered to encourage its use. Further research and development may increase the demand for biobased diesel fuel in the long term.

In the United States, biodiesel would be unlikely to completely replace petroleum-based diesel. Even if all of the vegetable oil currently produced in the United States, about 3.1 billion gallons per year, went into biodiesel production, plant-based diesel production could provide only 6.4 percent of the nations annual diesel consumption of 45 billion gallons (Harsch, 1992). Production of 3 billion gallons of biodiesel necessary for agricultural uses would require farmers to dedicate 40 million to 60 million acres to biodiesel crops (Harsch, 1992). Introduction of biodiesel as a blend with conventional diesel fuel is a more feasible goal in the United States and one that could have significant benefits in areas where the environment is sensitive to disruption by conventional diesel emissions or spills.

Biodiesel is made by transesterifying plant oils with methanol in the presence of a catalyst to produce fatty acid methyl esters. Methanol for the reaction is readily available from biomass, natural gas usage, or coal. Oils that can be processed into biodiesel include soybean, canola, and industrial rapeseed (Harsch, 1992). If the reacted oils have the correct carbon chain length, the fatty acid methyl esters will have chemical characteristics similar to those of conventional diesel fuel when they combust in modern diesel engines. Biodiesel is usually mixed with petroleum-based diesel fuel in a ratio of 20 percent biodiesel to 80 percent diesel fuel (B20). The U.S. Department of Energy has moved to the rule-making process for inclusion of B20 as an approved alternative fuel under the Energy Policy Act of 1992. If this commercial acceptance occurs in the private sector, fleets of small diesel engines will be able to meet more stringent alternative fuel guidelines with biodiesel.

Biodiesel does confer some environmental benefits. One advantage of biodiesel over petroleum-derived diesel is the virtual absence of sulfur and aromatic compounds (Abbe, 1994). Further, combustion of biodiesel produces lower emissions of carbon monoxide, unburned hydrocarbons, and particulate matter than combustion of petroleum-based diesel (Abbe, 1994). Consideration of emissions is particularly important in urban areas suffering from poor air quality. Biodiesel may be valuable in the future because the fuel can be used in todays diesel engines without modification and in various blends without negative impacts on engine performance (Hayes, 1995).

An increased focus on biodiesel largely results from its success in Europe. The crop of choice in Europe has been rapeseed, and the European Union has implemented subsidies for farmers growing oilseed crops to promote biodiesel production. European production of biodiesel and implementation of government policies to promote its use have progressed relative to the United States. A liter of biodiesel requires 3.3 kilograms of soybean oil and other inputs valued between $0.50 and $0.70. If soybean oil costs $0.25 per pound, biodiesel must cost at least $2.33 per gallon excluding taxes, or at least four times the cost of tax-free petroleum-based diesel (Hayes, 1995). The USDA estimated a hypothetical market price of $4.25 per gallon for biodiesel (ERS, 1996). As a result of these high costs, biodiesel may be used only where it is mandated, such as in urban transit fleets and government-owned diesel vehicles, which limits the ultimate market size and encourages vehicle owners to seek less expensive alternatives (Hayes, 1995). Some research on other plant-based diesel fuel alternatives may be warranted. Direct substitution of plant oils for diesel fuel would be cheaper than the manufacture of biodiesel because the transesterification process imposes significant additional costs. Unfortunately, the high viscosity of the oils causes poor atomization and creates flow characteristics that are generally incompatible with present-day diesel engines (Harsch, 1992).

 


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